Control questions
Q1. Define the term salt.
Answer: In chemistry, a salt is an ionic compound that can be formed by the
neutralization reaction of an acid and a base. Salts are composed of related
numbers of cations (positively charged ions) and anions (negative ions) so that
the product is electrically neutral (without a net
charge).
Q2. What is a hydrolysis?
Answer: The reaction of an anion or cation with water accompanied by cleavage
of O–H bond is called hydrolysis. The term hydrolysis is derived from hydro, meaning water, and
lysis, meaning breaking. It may be noted that in anionic hydrolysis shown in the
solution becomes slightly basic (pH > 7) due to the generation of excess
OH– ions. In cationic
hydrolysis there is excess of H+ ions which makes the solution
slightly acidic (pH < 7).
Q3. How is cation hydrolysis different from anion
hydrolysis?
Answer: When a neutral salt is dissolved in water, it will break down into
its consituant ions. The positive ions are called cations, while the negative
ions are the anions.
Q4. What is a hydrolysis reaction?
Answer: "A Hydrolysis is the process in which water is used to split a
substance into smaller particles". Which would make a hydrolysis reaction, a
reaction in which water is used to split a substance into smaller particles.
Q5. What is the order of a hydrolysis reaction?
Answer: Hydrolysis in a chemistry a double decomposition reaction withaqua
(Water) as one of the reactants. Thus, if a compound is denotedby the formula xy
in which y and x are atoms then water isrepresented by the formula HOH, the
hydrolysis reaction may berepresented by the reversible chemical equation xy +
HOH → xH +yOH. The reactants other than water, and the products ofhydrolysis,
may be neutral molecules-as in most hydrolysesinvolving organic compounds as in
hydrolyses of salts, acids, andbases.
Q6. What are dehydration and hydrolysis reactions?
Answer: Dehydration syntheses: the removal of water to join monomers into
macromolecules Hydrolysis: the addition of water to separate macromolecules
Maltose is made by dehydration synthesis.
Q7. What is difference between hydration and
hydrolysis?
Answer: Hydration is when water molecules (or more formally a hydroxyl and a
hydrogen ions) are incorporated into a molecule without breaking it. Hydrolysis
is when a molecule is broken in two pieces by the incorporation of a hydroxyl
and a hydrogen ion. One half of the original molecule will bond with the
hydroxyl the other with the hydrogen ion.
Q8. Difference between acidic hydrolysis and basic hydrolysis in
amide?
Answer: Acidic Conditions: Begin by protonating the oxygen in the carbonyl
group, in the next step you can add water to the activated nucleophile to make
the tetrahedral intermediate. The rest of the reaction are acid base reactions
to maintain an acidic equilibrium and end up the ammonium as the acid catalyst.
Basic Conditions: You may begin by adding the hydroxyl group to the carbonyl
carbon and then protonating the now negative oxygen from the previous alkene
with the proton left over by the hydroxyl group (originally it was water). You
need to dissociate your tetrahedral intermediate by protonating the amide and
then pushing it out when you take the proton by the oxygen pushing the electrons
to make a double bond to form the carbonyl group and push out the
NH3. In the end base deprotonates the carboxylic acid and you wind up
with ammonium. The main key is equilibrium, you end up with a negative charged
ion at the end because you maintain a negative charge in a basic
mechanism.
Q9. Can H2O2 used for
hydrolysis?
Answer: Yes, it can. The equation is H2O2 (aq) +
H2O (l) → HO2- (aq) +
H3O+ (aq).
Q10. Hydrolysis is involved in?
Answer: Hydrolysis is involved in maltose to glucose digestion. Maltose,
astarch, gets hydrolyzed into a couple remains of glucose in thiscarbohydrate
digestion.